Grafting Compounding

Twin screw lines that graft maleic anhydride (MAH) onto PP or PE inside the extruder. The product is the coupling agent for fibre- and mineral-filled PP, and the compatibilizer for polymer alloys.

  • PP-g-MAH · PE-g-MAH
  • Liquid dosing
  • Vacuum degassing
PP grafting compounding line with feeding tower and twin screw extruder

Four ingredients, one reaction

The peroxide opens sites on the polymer chain; MAH attaches there. Acetone carries both into the extruder as one liquid.

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Basic formula
  • PP / PE
  • MAH
  • DCP
  • Acetone
  • Additives

PP / PE

The backbone that is grafted.

Maleic anhydride (MAH)

The polar group grafted onto the chain.

DCP

Dicumyl peroxide, the initiator.

Acetone

Solvent for MAH and DCP; removed under vacuum.

Polymer and liquid by weight, solvent out by vacuum

Two loss-in-weight feeders keep the ratio of polymer to reactive liquid constant. What is not grafted, and the acetone, has to leave before the die.

PP / PEloss-in-weight feeder MAH + DCP in acetoneagitator · liquid LIW feeder grafting reaction vacuum degassingacetone · unreacted MAH water-cooledstrand
Schematic of the process described on this page; screw configuration and zone positions are not shown.
Feeding platform of a PP grafting line
Feeding platform.
Agitated tank and pump for the MAH and DCP solution
Liquid tank and pump.
  • One loss-in-weight feeder for the polymer.
  • MAH and DCP dissolved in acetone and mixed by an agitator; a second loss-in-weight feeder doses the mixed liquid.
  • A good vacuum system for degassing.
  • Water cooling strand pelletizing.

Where grafted PP and PE go

Grafted polyolefin is an ingredient in other compounds. These are the jobs it does.

RoleIn compounds of
Coupling agentbonds filler to PPPP with glass fibre, carbon fibre or wood fibre; PP with mineral powder
Compatibilizerjoins two polymersPP/PA6, ABS/PA6, PA/EPDM alloys

SolutionEngineering plastic SolutionWPC wood plastic composites SolutionFiller masterbatch

Strand or underwater

The grafting lines described here use water-cooled strands. Our underwater pelletizing systems have also run MAH-grafted PP and PE for compatibilizer producers.

SAT65 twin screw extruder with water cooling strand pelletizer
Water-cooled strand

As specified for grafting

Strands cooled in a water bath and cut by a strand pelletizer.

Underwater pelletizing system
Underwater

Enclosed cutting at the die face

The enclosed process helps manage dust and strand breakage in highly modified compounds.

Get a quote

Tell us the base polymer and its melt flow, the MAH and peroxide levels you work with, the end use of the grafted product and the output you need. We will propose the liquid dosing, degassing and pelletizing.

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  1. 01Polymer, MAH & peroxide
  2. 02Liquid dosing & degassing
  3. 03Strand or underwater
Souder Chen

Souder Chen

Head of Compounding Division

With USEON since 2008. Twin screw compounding, devolatilization and recycling lines.

Grafting Compounding

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Regarding: Grafting Compounding

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